Product ID:GOULD LIQUID TONER, 23-5111-05
MSDS Date:12/22/1993
FSC:6850
NIIN:01-362-3895
MSDS Number: BXTKQ

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

MINERAL SPIRITS; (ISOPARAFFINIC HYDROCARBON)

CAS: 64475-85-0

RTECS: PY8240000

Fraction By Weight: 98-99.5%

OSHA PEL N/K

ACGIH TLV: N/K

ROSIN; (HYDROGENATED ROSIN)

CAS: 65997-06-0

Fraction By Weight: 0.6%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 0.55%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

PRLNGD/RPTD CONT MAY RSLT IN DEFAT LEADING TO

RTECS: 9999999ZZ

OF PROD. BASED ON POTNTL ACUTE EFTS FROM ASPIR OF

RTECS: 9999999ZZ

ING 1 HAS CAUSED SLIGHT EFTS

RTECS: 9999999ZZ

VAP CONCS, THESE CMPDS HAVE SHOWN EFTS SIMILAR TO CNS

RTECS: 9999999ZZ

TO RATS OF SIMILAR HYDROCARBON @ CONCS >/EQUAL TO 300

RTECS: 9999999ZZ

ANEMIA. SIGNIFICANCE OF EFTS FOR HUMANS IS

RTECS: 9999999ZZ

OR REPORTED TO BE DEVELOPMENTAL/REPRO TOXIN. INHAL OF

RTECS: 9999999ZZ

SHOWED THESE CMPDS NOT TO BE TERATOGENIC (CAUSE

RTECS: 9999999ZZ

KNOWN OR REPORTED TO BE MUTAGENIC. ING 1 HAS BEEN

RTECS: 9999999ZZ

SALMONELLA GENE MUTATION ASSAY, MOUSE MICRONUCLEUS

RTECS: 9999999ZZ

RATS. ALL STUDIES HAVE SHOWN ING 1 NOT TO BE

RTECS: 9999999ZZ

IF PERSON

RTECS: 9999999ZZ

MOVE TO FRESH AIR UNTIL SYMPS DISAPPEAR. IF BRTHG IS

RTECS: 9999999ZZ

MD. IN EVENT THAT AN INDIVIDUAL INHALES ENOUGH VAP

RTECS: 9999999ZZ

AIR AT ONCE & MD SHOULD BE CALLED IMMED. IF BRTHG

RTECS: 9999999ZZ

CASES, ENSURE ADEQ VENT & PROVIDE RESP PROT BEFORE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50(ORAL,RAT):>5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING:DO NOT TAKE INTERNALLY. ASPIR
HAZ. IF ASPIR CAN CAUSE CHEM PNEUM. SKIN, EYE & MUC MEMB IRRIT.
OVEREXP TO VAPS MAY CAUSE CNS DEPRESS. RPTD CONT MAY DEFAT SKIN &
CAUSE DERM. ACUTE:INHAL:VAPS MAY BE IRRIT TO NOSE, THROAT, MUC
MEMBS & UPPER RESP TRACT. AT HIGH CONCS, MAY CAUSE CNS DEPRESS
W/SYMPS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:INCLUDING HDCH, GIDD, DIZZ & NAUS.
SKIN:CONT MAY CAUSE SLIGHT TO MOD IRRIT W/REDNESS & DRYING OF
CONTACTED AREA. EYES:CONT/EXPOS TO HIGH VAP CONCS MAY CAUSE SLIGHT
REVERSIBLE IRRIT W/SYMPS O F TEARING & ITCHING. DIRECT CONT W/LIQ
WOULD BE EXPECTED TO CAUSE SIMILAR SYMPS. INGEST:MAY CAUSE (SUPP
DATA)
Medical Cond Aggravated by Exposure:PSORIASIS AND OTHER SKIN DISORDERS,
PRE-EXISTING EYE AND RESPIRATORY DISORDERS.

First Aid:EYES:IMMED FLUSH W/LG AMTS OF WATER FOR @ LST 15 MIN, OCCAS
LIFTING UPPER & LOWER EYELIDS. IF IRRIT DEVELOPS, CALL MD.
SKIN:IMMED FLUSH W/WATER FOR 15 MIN. WASH CONTAM AREA W/SOAP &
WATER. IF IRRIT DE VELOPS, CALL MD. IF CLTHG COMES IN CONTW/PROD,
LAUNDER BEFORE RE-USE. INGEST:IMMED DRINK LG QTYS OF WATER. DO NOT
INDUCE VOMIT. CALL MD AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF
PERSON IS (ING 15)

Flash Point Method:TCC
Flash Point:120F,49C
Lower Limits:0.7%
Upper Limits:7.0%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . USE WATER TO COOL CONTAINERS EXPOSED TO
FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:CONTACT:OCEAN AT TELEPHONE # THAT APPEARS ON
FIRST PAGE OF MSDS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
PLACE. DO NOT STORE AT TEMPERATURES ABOVE:30C (102F).
Other Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES
AND CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER.

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR IF
EXPOSURES ABOVE THE RECOMMENDED EXPOSURE LEVEL ARE POSSIBLE.
NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MAINTAIN LEVELS TO BELOW
THE RECOMMENDED EXPOSURE LEVEL.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:PROT CLTHG TYPE:IMPERVIOUS BOOTS, APRON,
PROT SUIT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:GASTROENTERITIS W/ANY/ALL OF FOLLOWING SYMPS:NAUS, LT
HEAD, DIARR & VOMIT. ASPIR OF ING 2 INTO LUNGS SHOULD BE AVOIDED.
ASPIR MAY CAUSE PULM (LUNG) EDEMA, CONGESTION, PNEUM & MAY BE FA
TAL. CHRONIC:INHAL:RPTD EXPOS IS NOT KNOWN/RPTD TO CAUSE
SIGNIFICANT EFTS OTHER THAN THOSE OF ACUTE EXPOS. (ING 4)

Boiling Pt:B.P. Text:>335F,>168C
Vapor Pres:5-10 @ 25C
Vapor Density:5.0-5.3
Spec Gravity:0.74-0.76
Evaporation Rate & Reference:0.1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK LIQUID WITH A FAINT HYDROCARBON ODOR.
Percent Volatiles by Volume:95-98

Stability Indicator/Materials to Avoid:YES
STOR/TRANSPORT:STRONG OXIDIZERS. PACKAGING:PLASTIC CNTNRS CONTAINING
HYDROCARBON-LEACHABLE ADDITIVES & PLASTICIZERS.
Stability Condition to Avoid:STATIC DISCHARGE MAY CAUSE IGNIT AT TEMPS
AT/> FL PT. SPKS, OPEN FLAMES, SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:CARE MUST BE TAKEN TO PVNT ENVIRON CONTAM FROM
USE OF MATL. USER HAS RESPONSIBILITY TO DISPOSE OF UNUSED MATL,
RESIDUES & CNTNRS IN COMPLIANCE W/ALL RELEVANT LOC, STATE & FED
LAWS & REGS REGARDING TRE ATMENT, STOR & DISP FOR HAZ & NONHAZ
WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.